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-AMINOACID-N-CARBOXY-ANHYDRIDES AND RELATED HETEROCYCLES

Kricheldorf

Oprawa:
MIĘKKA

Wydawca:
Springer Berlin Heidelberg

ISBN:
9783642715884

558,56 PLN
Wysyłamy w 28 dni

Opis produktu

1. Synthesis and Characterization of NCAs. 1.1 Syntheses of ?Amino Acid NCAs. 1.2 Syntheses of and ?Amino Acid NCAs. 1.3 Thio Analogs of ? and Amino Acid NCAs. 1.4 Purification and Titration of NCAs. 1.5 IR Spectroscopy. 1.6 NMR Spectroscopy. 1.7 Tables of NCAs. References. 2. Oligomerization and Polymerization of NCAs: Chemical Aspects.. 2.1 Background. 2.2 Stoichiometric Reactions of NCAs. 2.2.1 Reactions with Protic Nucleophiles. 2.2.2 Various Reactions. 2.3 Stepwise Peptide Syntheses. 2.3.1 With NUnsubstituted NCAs. 2.3.2 With TVSubstituted NCAs. 2.4 Polymerization with Protic Nucleophiles. 2.4.1 Primary Amines. 2.4.2 Secondary Amines. 2.4.3 The Carbamate Mechanism. 2.5 Tertiary Amines. 2.5.1 Trialkylamines. 2.5.2 Pyridines. 2.6 Metal Salts and Organometallic Compounds. 2.6.1 Various Anions. 2.6.2 Organometallic Initiators. 2.7 Thermal Polymerizations. 2.8 ?Amino Acid NCA and Thio NCAs. 2.8.1 ? and ?Amino Acid NCAs. 2.8.2 Thio Analogs of NCAs. References. 3. Polymerization of NCAs: Physical Aspects. 3.1 Determination of Molecular Weights. 3.1.1 Endgroup Analyses. 3.1.2 Physical Methods. 3.2 Molecular Weight Distributions and Polydispersity. 3.3 ChainEffect Polymerization. 3.3.1 The Chain Effect of Polysarcosine. 3.3.2 The Helical Chain Growth. 3.3.3 Template Polymerizations. 3.4 Secondary Structure of Solid Polypeptides. 3.4.1 Definitions and Methods. 3.4.2 Secondary Structure and Crystal Grow

Wymiary: 399 gr 170 mm 242 mm

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